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WhatsApp: +86 182217550731 1 Synthesis and molecular structure of arene ruthenium(II) 2 benzhydrazone complexes: Impact of substitution at chelating 3 ligand and arene moiety on antiproliferative activity 4 Mohamed Kasim Mohamed Subarkhan,† Rengan Ramesh,*,† and Yu Liu‡ 5 †Centre for Organometallic Chemistry, School of Chemistry, Bharathidasan University, 6 …
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WhatsApp: +86 18221755073[2] Among the methods of arene transformations, catalytic hydrogenation of aromatic compounds stands out as an environmentally friendly and highly efficient strategy for producing industrially ...
WhatsApp: +86 18221755073A convenient method for the synthesis of ruthenium(II) arene benzhydrazone complexes (1–6) of the general formula [(η 6-arene)Ru(L)Cl] (arene-benzene or p-cymene; L-monobasic bidentate substituted indole-3-carboxaldehye benzhydrazone derivatives) has been described.The complexes have been fully characterized via elemental analysis, IR, …
WhatsApp: +86 18221755073Monosubstituted benzenes are named in the same way as other hydrocarbons are, with -benzene as the parent name. C 6 H 5 Br denotes bromobenzene, C 6 H 5 NO 2 denotes nitrobenzene, and C 6 H 5 CH 2 CH 2 CH 3 denotes propylbenzene.; Alkyl-substituted benzenes are termed differently depending on the size of the alkyl group.
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WhatsApp: +86 18221755073Ruthenium(II) arene PTA (RAPTA) complexes: impact of enantiomerically pure chiral ligands Dalton Trans. 2013 Feb 14;42(6):2008-14. doi: 10.1039/c2dt32333h. Authors Kelly J Kilpin 1, Shona M Cammack, Catherine M Clavel, Paul J …
WhatsApp: +86 18221755073Arene dearomatization reactions are an important class of synthetic technologies for the rapid assembly of unique chemical architectures. Herein, we report a catalytic protocol …
WhatsApp: +86 18221755073Organometallic ruthenium(II) arene complexes containing the PTA ligand ([Ru(η 6-arene)Cl 2 (PTA)], PTA = 1,3,5-triaza-7-phosphatricyclo-[3.3.1.1]decane, termed RAPTA) show pharmacologically relevant anti-tumour properties in vitro.Two new enantiomeric pairs of RAPTA compounds, containing the chiral arene (R)- or (S)-2-phenyl-N-(1 …
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WhatsApp: +86 18221755073It would, of course, be even worse for larger arene molecules. Reactivity. Benzene. It has already been pointed out above that benzene is resistant to addition reactions. Adding something new to the ring would need you to use some of the delocalised electrons to form bonds with whatever you are adding. That results in a major loss of stability ...
WhatsApp: +86 18221755073Contributors and Attributions. John D. Robert and Marjorie C. Caserio (1977) Basic Principles of Organic Chemistry, second edition. W. A. Benjamin, Inc., Menlo Park, CA. …
WhatsApp: +86 18221755073Noncovalent interactions between π systems are determined by electrostatic factors, as Cozzi, Siegel, et al. have recently shown: thus, interactions between two aromatic rings in a face-to-face stacked geometry (see below) are most favorable when both rings have acceptor substituents A, and least favorable when both have donor substituents D. This …
WhatsApp: +86 18221755073Synthesis and molecular structure of arene ruthenium( ii ) benzhydrazone complexes: impact of substitution at the chelating ligand and arene moiety on antiproliferative activity. New Journal of Chemistry 2016, 40 (11), 9813-9823. DOI: 10.1039/C6NJ01936F. Hua-Ying Luo, Jin-Yu Li, Yue Li, Li Zhang, Jin-Yao Li, Dian-Zeng Jia, Guan-Cheng Xu. ...
WhatsApp: +86 18221755073Arene–arene interactions (also known as π–π-stacking interactions) are vital in biological interactions including the interactions between DNA and organic molecules. ... (8–11), …
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WhatsApp: +86 18221755073Arenes are aromatic hydrocarbons. The term "aromatic" originally referred to their pleasant smells, but now implies a particular sort of delocalised bonding (see below). The arenes …
WhatsApp: +86 18221755073Notably, it appears that substituents have an even larger impact on arene interactions in complexes with tilted and offset geometries such as those in proteins. These substituent effects were electrostatics-driven, although the dominating component in the interactions was dispersion. The results also showed that arenes substituted with halogens ...
WhatsApp: +86 18221755073Semantic Scholar extracted view of "Assessment of antiproliferative activity of new half‐sandwich arene Ru (II) furylbenzhydrazone complexes" by Ramya Prabaharan et al. ... The results highlight the impact that a simple ligand modification such as the reduction of an imine moiety can have on both the catalytic and biological activities of ...
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WhatsApp: +86 18221755073Next, we analyzed the impact of ring sizes in arene-perfluoroarene interactions by comparing six complexes with differing ring sizes: 1a·4, 2a·4, 3a·4, 1a·5a, 2a· 5a, and 3a·5a (Figure 7a). We found that increasing the surface area of either the aryl or perfluoroaryl unit increases the binding affinities of the arene-perfluoroarene complexes.
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